Clouding of Pressed Potassium Bromide Powder
- 1 March 1972
- journal article
- research article
- Published by SAGE Publications in Applied Spectroscopy
- Vol. 26 (2) , 247-251
- https://doi.org/10.1366/000370272774352236
Abstract
The monomolecular layer of water adsorbed on KBr particles is responsible for clouding of disks pressed from finely ground powder. Cloudiness is caused by formation of a multitude of cracks in the disk. The initial cracking can be observed with a low power optical microscope and the extensive cracking in the fully cloudy region is observable with a scanning electron microscope. It is suggested that adsorbed water promotes recrystallization, generating weak zones in the workhardened, elastically stressed disk which fails by cracking.Keywords
This publication has 11 references indexed in Scilit:
- The influence of moisture on potassium bromide disks used in infrared spectrometrySpectrochimica Acta, 1962
- Infra-red spectra in the solid state: Anomalous hydroxyl-group absorption in potassium halide disksSpectrochimica Acta, 1959
- Potassium Bromide Pellet TechniqueAnalytical Chemistry, 1959
- The infra-red analysis of solid substances. A reviewThe Analyst, 1959
- Quantitative Application of Sample Dispersion in Potassium Bromide for Infrared Analysis of SteroidsAnalytical Chemistry, 1958
- Solid State Anomalies in Infrared SpectroscopyThe Journal of Physical Chemistry, 1957
- Quantitative Infrared Analysis of Solids in Potassium Bromide Using an Internal StandardAnalytical Chemistry, 1957
- Quantitative Application of Potassium Bromide Disk Technique in Infrared SpectroscopyAnalytical Chemistry, 1955
- Application of Infrared Spectrophotometry to Quantitative Analysis in Solid PhaseAnalytical Chemistry, 1955
- Infrared Analysis of Solids by Potassium Bromide Pellet TechniqueAnalytical Chemistry, 1954