Reaction of ethoxide with p-nitrophenyl benzenesulphonate. Catalysis and inhibition by alkali metal ions; contrast with p-nitrophenyl diphenylphosphinate
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 1566-1567
- https://doi.org/10.1039/c39890001566
Abstract
In the reaction of p-nitrophenyl benzenesulphonate with ethoxide in ethanol, some alkali metals (Na+, K+, Cs+) cause a rate acceleration, while Li+ causes a rate retardation; the results are analysed in terms of interactions of metal ions with the ground state and the transition state of the reaction.Keywords
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