A Correlation between Critical Volumes and Work Function Data for Electrons in Liquid Hydrocarbons

15 October 1973

journal article
Published by Canadian Science Publishing in Canadian Journal of Chemistry

Vol. 51 (20) , 3443-3444
https://doi.org/10.1139/v73-512

Abstract

Electron-molecule hard-core radii determined with the aid of Springett, Jortner, and Cohen's quasi-free electron theory from electron work function data are shown to correlate with the critical volumes of several hydrocarbons. The radii are approximately equal to the van der Waals radii determined from the critical volumes.

Keywords

FUNCTION
DER
COHEN'S
VAN
HARD
QUASI
WAALS
CRITICAL VOLUMES
JORTNER
SPRINGETT

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