Triphosgene, a Crystalline Phosgene Substitute
- 1 September 1987
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 26 (9) , 894-895
- https://doi.org/10.1002/anie.198708941
Abstract
Thermally stable, not very volatile, easy to transport and to store, accurately dosable—these are the advantages of bis(trichloromethyl) carbonate 1 as a substitute for phosgene. In addition, stoichiometric amounts of 1 suffice for chloroformylations, carbonylations, chlorinations, and dehydrations, which, moreover, proceed in good to very good yields. equation imageKeywords
This publication has 9 references indexed in Scilit:
- TRICHLOROMETHYL CHLOROFORMATE AS A PHOSGENE EQUIVALENT: 3-ISOCYANATOPROPANOYL CHLORIDEOrganic Syntheses, 1979
- Isocyanide Synthesis with DiphosgeneAngewandte Chemie International Edition in English, 1977
- Isocyanid‐Synthese mit DiphosgenAngewandte Chemie, 1977
- Trichloromethyl chloroformate. Reaction with amines, amino acids, and amino alcoholsThe Journal of Organic Chemistry, 1976
- Chemistry of phosgeneChemical Reviews, 1973
- The Kinetics of the Thermal Decomposition of Trichloromethyl ChloroformateJournal of the American Chemical Society, 1933
- Über die Ester der halogenierten Alkohole. (II. Mitteilung). „Über die Reaktionen der Ester, die die Trichlormethoxylgruppe enthalten”︁Journal für Praktische Chemie, 1930
- Ueber gechlorte Ameisensäuremethyläther und verwandte KörperJournal für Praktische Chemie, 1887
- Kohlensaures MethylEuropean Journal of Inorganic Chemistry, 1880