Fe57 Mössbauer Effect in Ferrocene Derivatives
- 1 May 1963
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 38 (9) , 2106-2111
- https://doi.org/10.1063/1.1733940
Abstract
The hyperfine structure in the Mössbauer spectrum of Fe57 in ferrocene and in related compounds shows that the bonding of the iron atom is not affected by ring substitution. The temperature dependence of the fraction of recoil‐free absorption events in these compounds indicates that the Debye temperature is low (∼150°K) and that the optical modes make only a minor contribution to the reduction of the recoil‐free fraction at low temperature.Keywords
This publication has 17 references indexed in Scilit:
- Fe57 Mössbauer Resonance and Comparison of Bonding in C8H8Fe2(CO)6 and C8H8Fe(CO)3Journal of the American Chemical Society, 1962
- Quadrupolaufspaltung und Isomerieverschiebung der 14,4 keV ?-Linie von Fe57 in metall-organischen EisenverbindungenThe European Physical Journal A, 1962
- The m$ouml$ssbauer effectReports on Progress in Physics, 1962
- Hyperfine Structure of Divalent and Trivalentin Cobalt OxidePhysical Review B, 1961
- Electric Quadrupole Splitting and the Nuclear Volume Effect in the Ions ofPhysical Review Letters, 1961
- The vibrational spectra and structure of ferrocene and ruthenoceneSpectrochimica Acta, 1958
- Über einige 1.1′‐Disubstitutionsprodukte des FerrocensEuropean Journal of Inorganic Chemistry, 1956
- Spectrometry of the Neutrino Recoils of Argon-37Physical Review B, 1955
- The Thermodynamic Functions of Bis-cyclopentadienyl Iron, Bis-cyclopentadienylnickel and Bis-cyclopentadienylrutheniumJournal of the American Chemical Society, 1955
- The Preparation and Some Properties of the Cobalticinium SaltsJournal of the American Chemical Society, 1952