High energy photoelectron spectroscopy of transition metal complexes. Part 2.—Metallocenes
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics
- Vol. 69, 559-562
- https://doi.org/10.1039/f29736900559
Abstract
Metal and core electron binding energies of the metallocenes of the first row transition metals are reported and discussed with the aid of approximate molecular orbital calculations. In all cases it is found that the metal atom is positively charged. The measured splitting of the metal 3s photoelectron peaks is interpreted in terms of spin delocalization in these molecules.Keywords
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