The Thermal Decomposition of CF3I in Ar
- 1 September 1984
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 57 (9) , 2661-2662
- https://doi.org/10.1246/bcsj.57.2661
Abstract
The thermal decomposition of CF3I behind reflected shock waves was studied by means of the UV absorption over the temperature range of 935–1235 K and in the density range of 6.3×10−6–3.8×10−6 mol cm−3. The decomposition rate was in the fall-off region, and the main process was the C-I bond fission. The rate constants corresponding to the limiting high- and low-pressure regions were determined to be; k ∞=1014.67exp(−27200⁄T)s−1 and; k 0⁄[Ar]=1014.71exp(−15000⁄T)cm3mol−1s−1.This publication has 6 references indexed in Scilit:
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