The effect of conformation on nuclear quadrupole coupling constants of α-chloro-ethers
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 7,p. 425b-426
- https://doi.org/10.1039/c2970000425b
Abstract
The difference in the bond length between axial and equatorial carbon–chlorine bonds in chlorodioxans is paralleled by a large change in the 35Cl nuclear quadrupole coupling constant and both these effects are compatible with an orientation-dependent conjugative interaction between the oxygen atom and the carbon–chlorine bond.Keywords
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