Differential scattering of spin ± (1/2) polarized neutrons by chiral systems. I. Theory
- 15 December 1977
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 67 (12) , 5702-5713
- https://doi.org/10.1063/1.434825
Abstract
A theoretical model is developed for treating the scattering of longitudinally polarized neutrons by a chiral array of nuclei. The model is restricted to consideration of nonmagnetic scattering systems comprised of ’’spinless’’ nuclei, and only forward scattering is considered. The differential scattering of spin ± (1/2) polarized neutrons is presumed to arise via a ’’spin–orbit’’ coupling mechanism in which the spin of the neutron is coupled to the orbital (vibrational) motions of the nuclei in the neutron–nuclei interaction region. Only low‐energy neutron scattering by vibrational excitations (or deexcitations) is considered. Neutron–nuclei interactions are described in terms of (1) neutron absorption–emission processes; (2) neutron reflection processes; and (3) neutrons moving through the (long‐range) Coulombic field of the nuclei. General expressions are developed for the differential scattering amplitudes of spin ± (1/2) polarized neutrons interacting with nuclei undergoing chiral vibrational motion.Keywords
This publication has 6 references indexed in Scilit:
- General theory of circularly polarized emission and magnetic circularly polarized emission from molecular systemsThe Journal of Chemical Physics, 1976
- Neutron Optical Activity Through Spin–Orbit InteractionCanadian Journal of Physics, 1975
- Rayleigh and Raman Optical ActivityAnnual Review of Physical Chemistry, 1975
- Circular dichroism and optical rotationChemical Reviews, 1975
- Vibrational circular dichroism observed in crystalline α-NiSO4 · 6H2O and α-ZnSeO4 · 6H2O between 1900 and 5000 cm−1The Journal of Chemical Physics, 1973
- On the Polarization of Fast NeutronsPhysical Review B, 1948