[MnM(egta)]. 8H2 = (M = Mn, Cd): Verbindungen mit einem neuartigen zweidimensionalen magnetischen Gitter
- 1 April 1993
- journal article
- zuschrift
- Published by Wiley in Angewandte Chemie
- Vol. 105 (4) , 637-639
- https://doi.org/10.1002/ange.19931050442
Abstract
Ausgedehnte schichtartige Netzwerke, in denen M2+ und Mn2+ acht‐ (durch egta4−) bzw. sechsfach koordiniert sind, liegen in den Titelverbindungen vor. Dies führt bei der Mn2‐Verbindung zu dem rechts skizzierten neuartigen zweidimensionalen Gitter mit zwischen den Schichten kurzreichweitigen antiferromagnetischen Austauschwechselwirkungen. H4egta = Ethylendioxybis(ethylennitrilo)tetraessigsäure; die Kreise symbolisieren magnetisch inäquivalente MnII‐Ionen. magnified imageKeywords
This publication has 11 references indexed in Scilit:
- From 1-D to 3-D ferrimagnets in the EDTA family: magnetic characterization of the tetrahydrate series MtM(M'EDTA)2.cntdot.4H2O [Mt, M, M' = cobalt(II), nickel(II), zinc(II)]Journal of the American Chemical Society, 1991
- Magnetic interactions and single-ion zero-field-splitting effects in the two-sublattice manganese chain MnMn(EDTA).cntdot.9H2O: magnetism and single-crystal EPR spectraInorganic Chemistry, 1991
- Magnetic Molecular MaterialsPublished by Springer Nature ,1991
- Introduction to Low-Dimensional Magnetic SystemsPublished by Springer Nature ,1990
- Toward molecular magnets: the metal-radical approachAccounts of Chemical Research, 1989
- Highly polydentate ligands. 5. Structures of alkaline-earth complexes of the calcium-selective ligand EGTA4- (H4EGTA = 3,12-Bis(carboxymethyl)-6,9-dioxa-3,12-diazatetradecanedioic acid)Inorganic Chemistry, 1988
- Polydentate chelates. 3. Structures of egta4–chelates of manganese(II) and copper(II): Sr[Mn(egta)].7H2O and [Cu2(egta)(OH2)2].2H2OActa Crystallographica Section C Crystal Structure Communications, 1988
- Calcium-selective ligands. 2. Structural and spectroscopic studies on calcium and cadmium complexes of EGTA4- [H4EGTA = 3,12-bis(carboxymethyl)-6,9-dioxa-3,12-diazatetradecanedioic acid]Journal of the American Chemical Society, 1987
- Calcium-selective ligands. 1. Structure of 3,12-bis(carboxymethyl)-6,9-dioxa-3,12-diazatetradecanedioic acid (H4egta)Acta Crystallographica Section C Crystal Structure Communications, 1986
- The quadratic-layer antiferromagnetJournal of Physics and Chemistry of Solids, 1970