Carbon-13 n.m.r. study of rhodium carbonyl clusters under high pressures of CO/H2
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 7,p. 331-332
- https://doi.org/10.1039/c39810000331
Abstract
High-pressure 13C n.m.r. spectra (850 bar, CO:H2= 2·1:1) show that [Rh12(CO)30]2– is converted cleanly into [Rh5(CO)15]– and that interexchange of carbonyls with carbon monoxide under high pressure is slow on the n.m.r. time scale.Keywords
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