Receptors for the hydrazinium ion. Simultaneous first- and second-sphere coordination inside organopalladium crown ether complexes
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 24,p. 1848-1850
- https://doi.org/10.1039/c39930001848
Abstract
Organopalladium crown ether complexes are employed to bind the hydrazinium ion, [NH2NH3]+, via simultaneous first- and second-sphere coordination featuring σ-donation to Pd and hydrogen bonding to aliphatic ether oxygen atoms.Keywords
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