The First General Method for Stille Cross-Couplings of Aryl Chlorides
- 16 August 1999
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 38 (16) , 2411-2413
- https://doi.org/10.1002/(sici)1521-3773(19990816)38:16<2411::aid-anie2411>3.0.co;2-t
Abstract
A “one-two punch” comprising two commercially available reagents, PtBu3 and CsF, provides a practical and general solution for a long-standing limitation of the Stille reaction—the inability to couple inexpensive and readily available aryl chlorides [Eq. (1); R1=OMe, NH2, o-Me, etc.; R=vinyl, allyl, Ph, Bu, etc.].This publication has 0 references indexed in Scilit: