Transition-metal complexes of crown ether benzodithiolenes
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 14,p. 2197-2207
- https://doi.org/10.1039/dt9930002197
Abstract
Three new dithiolene ligands have been synthesised, two of which have the novel feature of a crown ether ring attached directly to the benzene ring of an aryl dithiolene. Complexes with transition metals have been prepared and their 1H, 13C NMR, UV/VIS and electrochemical properties recorded. The information obtained appears to reflect variations in the degree of delocalisation in the metallodithiolene ring within the series of complex types.Keywords
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