Calculation of binding constants and bound chemical shifts for the association of lanthanide shift reagents with organic substrates
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 20,p. 1281-1282
- https://doi.org/10.1039/c29710001281
Abstract
By varying the ligand concentration the bound chemical shift and the equilibrium constant for the binding of ligand to lanthanide may be determined; studies of tris(dipivalomethanato)europium(III) complexes show that n-propylamine is bound more strongly than is neopentanol.Keywords
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