A Reinvestigation of the Structure of the Transition State in Peracid Epoxidations. α- and β-Secondary Isotope Effects
- 1 August 1997
- journal article
- research article
- Published by American Chemical Society (ACS) in The Journal of Organic Chemistry
- Vol. 62 (17) , 6083-6085
- https://doi.org/10.1021/jo970268h
Abstract
No abstract availableThis publication has 11 references indexed in Scilit:
- Secondary isotope effects in dioxirane epoxidations. Concerted or step-wise mechanism?Tetrahedron Letters, 1996
- Remote ε- secondary isotope effect in the reaction of tetracyanoethylene with 2,5-dimethyl-2,4-hexadiene. A step-wise mechanismTetrahedron Letters, 1996
- The endocyclic restriction test: an experimental evaluation of the geometry at oxygen in the transition structure for epoxidation of an alkene by a peroxy acidJournal of the American Chemical Society, 1991
- Convergent functional groups. 2. Structure and selectivity in olefin epoxidation with peracidsThe Journal of Organic Chemistry, 1986
- Theoretical investigation of the structure and rotational barriers of peroxyformimidic acid. The mechanism of stereomutation at the carbon-nitrogen double bondJournal of the American Chemical Society, 1981
- The mechanism of epoxidation of olefins by peracidsTetrahedron, 1976
- Transition state structure for peracid epoxidation. Secondary deuterium isotope effectsJournal of the American Chemical Society, 1975
- Organische peroxide—XITetrahedron, 1974
- Kinetics of the peracid oxidation of acetylenes. Electrophilic attack on phenylacetylenesThe Journal of Organic Chemistry, 1973
- The oxidation of olefins with perbenzoic acids. A kinetic studyJournal of the Chemical Society, 1955