Synthesis of Precursors to L-Ristosamine and L-Daunosamine from L-Lactic Acid.
- 1 January 1985
- journal article
- research article
- Published by Danish Chemical Society in Acta Chemica Scandinavica
- Vol. 39b (7) , 589-592
- https://doi.org/10.3891/acta.chem.scand.39b-0589
Abstract
Condensation of the protected L-lactaldehyde 4 with methyl 3-nitropropionate gave a mixture of nitro alcohols 5, which, in one step, was converted into a 2-5:1 mixture of nitro lactones 6 and 7. Hydrogenation, benzoylation and separation afforded the L-ristosamine precursor 8 and the L-daunosamine precursor 9.This publication has 4 references indexed in Scilit:
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- Convenient syntheses of L-digitoxose, L-cymarose, and L-ristosamineJournal of the Chemical Society, Perkin Transactions 1, 1982
- Structure and conformation of N-benzoyl derivatives of the biologically important 3-amino-2,3,6-trideoxy-L-hexoses and their synthetic precursor γ- and δ-lactones; a1H and13C nuclear magnetic resonance studyJournal of the Chemical Society, Perkin Transactions 1, 1982
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