Reactions of tris(triphenylphosphine)platinum(o) and tetrakis(triphenylphosphine)palladium(o) with oxygen and carbon dioxide
- 1 January 1968
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 561-563
- https://doi.org/10.1039/j19680000561
Abstract
The oxygen compounds (Ph3P)2MO2(M = Pd or Pt) have been prepared by the action of oxygen on (Ph3P)4Pd and (Ph3P)3Pt respectively. In presence of carbon dioxide the corresponding carbonato-complexes, (Ph3P)2MCO3, which may be isolated also as solvates, are obtained. The latter are characterised by spectroscopic and chemical techniques and some of their reactions described.Keywords
This publication has 0 references indexed in Scilit: