Selective palladium catalysed monohydroesterification of diols
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 1349-1351
- https://doi.org/10.1039/c39840001349
Abstract
Olefins react with diols (e.g. ethylene glycol) under oxidative carbonylation and acidic conditions, using palladium and copper (II) chloride as catalysts, to give hydroxy esters in good yields; this mild reaction (room temperature, 1 atm) is a regioselective one.Keywords
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