Synthesis of the Nephritogenoside Trisaccharide Unit Using Phenyl 1-Thioglycopyranoside Sulfoxides as a Glycosyl Donor

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Abstract
The nephritogenoside trisaccharide unit was synthesized under mild conditions using phenyl 1-thioglycopyranoside sulfoxides as glycosyl donors. In the coupling process neither thiophenyl nor trityl protecting groups are cleaved from the carbohydrate moieties demonstrating the utility of this method also for oligosaccharide block syntheses.

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