The diffusion potentials in electrolytic mixtures. II. The system “concentrated KCl/dilute HCl”
- 1 January 1939
- journal article
- research article
- Published by Wiley in Recueil des Travaux Chimiques des Pays-Bas
- Vol. 58 (2) , 99-106
- https://doi.org/10.1002/recl.19390580202
Abstract
The KCl‐bridge which is so frequently used in practice lacks its necessary theoretical foundation. Basing upon the differential equations of “free” diffusion, it is possible to develop a satisfactory theory which leads to reliable values for the diffusion potentials concerned. It is shown by a similar treatment that the assumption made in our previous paper, according to which the problem of free diffusion can be solved in terms of y = x/2 √ t entirely justified.Keywords
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