Cation Diffusion in Cr[sub 2]O[sub 3]

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Abstract
On employing a sectioning technique with Cr51 as the tracer, the diffusion of Cr ions in nitrogen‐equilibrated was determined from 1045° to 1550°C. Volume diffusion coefficients in hot‐pressed compacts of three different impurity levels conform to the expression . Additions of and do not cause a significant change. Use of lower density sintered compacts provides erroneous results. Conductivity measurements were performed in nitrogen, argon, and air over a wide temperature range; no dependence on oxygen partial pressure was observed. Calculated cation transference numbers vary from 10−3 to 10−6. Postulating a simplified model for the defect structure of , the activation enthalpy for hole motion is 8.4 kcal mole−1; the enthalpy of defect formation is 91 kcal mole−1; the activation enthalpy for cation motion is about 31 kcal mole−1.

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