Formation constants of chlorocadmium(II) and cadmium dichloride in aqueous melts of calcium dinitrate and calcium dinitrate–potassium nitrate
- 1 January 1976
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 2,p. 104-108
- https://doi.org/10.1039/dt9760000104
Abstract
Formation constants of [CdCl]+ and CdCl2 in aqueous melts of Ca[NO3]2·xOH2 and Ca[NO3]2·K[NO3]·xOH2(x= 3.5–7) have been determined at 50, 65, and 80 °C from e.m.f. measurements in suitable concentration cells. The results are discussed in terms of a quasi-lattice structure of aqueous melts, and a model is proposed which predicts the dependence of thermodynamic data for [CdCl]+ formation on the temperature and water content of the molten salt.Keywords
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