Preparation of XeOF3+·Sb2F11–and XeO2F+·Sb2F11–.19F nuclear magnetic resonance and Raman spectra of XeOF3+and XeO2F+
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 607-609
- https://doi.org/10.1039/c39720000607
Abstract
The 19F n.m.r. spectra of solutions in SbF5 and the Raman spectra of the solids show that the compounds XeOF4·2SbF5 and XeO2F2·2SbF5 have the ionic structures XeOF3 +·Sb2F11 – and XeO2F+·Sb2F11 –, that the XeOF3 + ion has the expected trigonal bipyramidal AX4E type structure and that the XeO2F+ ion has a pyramidal structure analogous to the isoelectronic XeO3.Keywords
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