Stereoselective Synthesis of Alcohols, XX. Diastereoselective Addition of γ‐Alkoxyallylboronates to Aldehydes
- 12 November 1985
- journal article
- research article
- Published by Wiley in European Journal of Organic Chemistry
- Vol. 1985 (11) , 2246-2260
- https://doi.org/10.1002/jlac.198519851115
Abstract
Both the (Z)‐ and the (E)‐γ‐alkoxy‐substituted allylboronates 1 and 3 have been prepared. They add to aldehydes with a diastereoselectivity generally exceeding 90% to give the syn‐ (2) and anti‐diol derivatives 4, respectively. The structure of one of these adducts has been established by conversion into exo‐brevicomin (26).Keywords
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