Chirality preservation in pyrrolinone iron tetracarbonyl complexes ? a route to enantiopure 5-substituted pyrrolinones
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 6,p. 617-618
- https://doi.org/10.1039/c39950000617
Abstract
The enantiopure iron complex 4 reacts under the influence of BF3·OEt2 with allylsilanes and enol acetates through a cationic intermediate in which the chirality of 4 is preserved, yielding enantiopure 5-substituted 3-pyrrolin-2-ones.Keywords
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