The catalysis of the stereospecific butadiene polymerization by Allyl Nickel and Allyl Lanthanide complexes — A mechanistic comparison
- 1 January 1995
- journal article
- research article
- Published by Wiley in Macromolecular Symposia
- Vol. 89 (1) , 393-409
- https://doi.org/10.1002/masy.19950890137
Abstract
A short overview on the general mechanistic principles of the allyl metal complex catalyzed stereo‐specific butadiene polymerization is given. The present state of knowledge on the mechanism of stereoregulation and in the understanding of the catalytic structure reactivity relationships is discussed comparatively for allyl nickel and allyl lanthanide catalysts.Keywords
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