Hydroxy group directed hydrogenation with rhodium and iridium catalysts. Synthesis of a protected chiral carbocyclic analogue of daunosamine
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 6,p. 330-332
- https://doi.org/10.1039/c39850000330
Abstract
Hydroxy group directed homogeneous alkene hydrogenation, with transition metal complexes of an appropriate mthylenecyclohexane derivative prepared from D-glucose proceeded stereospecifically from the more hindered side and allowed a chiral protected carbocyclic analogue of daunosamine to be prepared.Keywords
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