Five-co-ordinate rhodium(I) complexes with three metal–olefin bonds
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 8,p. 488-489
- https://doi.org/10.1039/c29700000488
Abstract
One-to-one complexes of the ligands (o-styryl)3P and (o-styryl)3As with RhX (X = Cl, Br, I) have been prepared: their properties indicate a pentaco-ordinate trigonal bipyramidal structure with the three olefin groups occupying the three trigonal (C3), and the halogen and phosphorus (or arsenic) atoms the apical, positions.Keywords
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