Treatment of data in step-response dielectric relaxation measurements
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics
- Vol. 68, 1890-1896
- https://doi.org/10.1039/f29726801890
Abstract
We report a satisfactory method for the direct conversion of step-response (transient) data (such as is obtained from the rate of discharge of a capacitor) into the frequency dependence of the complex relative permittivity. This computer-based method has no a-priori restriction on the shape of the loss peak or functional dependence of the decay response. In this it differs from a number of approaches described in the literature.1–4 The method herein described is compared to such other techniques for converting step-response data, and assessed in relation to the predicted behaviour for single and unresolved double Debye relaxations. The dielectric relaxation behaviour of a sample of poly(vinyl acetate) is also investigated using the described method of data analysis.Keywords
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