The chemistry of cyanoacetylenes. Part I. Reactions of nitrilium ions conjugated with acetylene
- 1 January 1969
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society C: Organic
- No. 3,p. 406-408
- https://doi.org/10.1039/j39690000406
Abstract
Although chlorocyanoacetylene is converted into an amide in sulphuric acid, cyanoacetylene itself is not. Nevertheless, both nitriles undergo the Ritter reaction with olefins and alcohols. N-(1,1-Dimethyl-2-chloroethyl)-propiolamide, one of the Ritter reaction products, gives an oxazoline on treatment with alkoxide, with accompanying addition of the alkoxide to the triple bond.Keywords
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