Unsymmetrically disubstituted ferrocenes. Part VIII. Synthesis and reactivity of some 2-substituted ferrocenylphosphines
- 1 January 1969
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society C: Organic
- No. 7,p. 1070-1072
- https://doi.org/10.1039/j39690001070
Abstract
The reaction of lithiated (dimethylaminomethyl)ferrocene with chlorodiphenylphosphine gave 2-(dimethylamino-methyl) ferrocenyldiphenylphosphine. This phosphinoferrocene has been converted into a variety of 1,2-disubstituted and 1,2,3-trisubstituted ferrocenes. Chlorodiphenylphosphine has been condensed with 1,1′-dilithio-ferrocene to give 1,1′-bisdiphenylphosphinoferrocene.Keywords
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