Preparation and Characterization of 61,6n-DI-O-(α-D-Galactopyranosyl)Cyclomaltooctaoses
- 1 January 2000
- journal article
- research article
- Published by Taylor & Francis in Journal of Carbohydrate Chemistry
- Vol. 19 (1) , 13-23
- https://doi.org/10.1080/07328300008544062
Abstract
Four positional isomers of 61,6n-di-O-(D-galactopyranosyl)cyclomaltooctaoses (cG8s, γ-cyclodextrins) (n = 2−5) were chemically synthesized using the trichloroacetimidate method. The desired compounds having two α-(1→6)-linkages were isolated from a mixture of configurational isomers by HPLC, and their structures were confirmed by 13C NMR spectroscopy and FAB-high resolution mass spectra (HRMS). The elution behavior of their four positional isomers on an ODS column by HPLC is discussed.Keywords
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