Tricontinuous Cubic Structures inCopolymer and Homopolymer Blends
- 29 October 2002
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 89 (20) , 205502
- https://doi.org/10.1103/physrevlett.89.205502
Abstract
Using the Monte Carlo lattice-simulation technique, we present numerical evidence of the formation of gyroid and nongyroid tricontinuous cubic phases in high polymeric systems of triblock copolymer and homopolymer blends. By increasing the volume fraction of homopolymer, a remarkable phase sequence (gyroid) (diamond) (primitive) is observed, which is common to certain surfactant systems. Our results indicate that the triblock copolymer system with blending homopolymers may be a zoo of cubic phases, suitable for comparative studies of these phases.
Keywords
This publication has 48 references indexed in Scilit:
- Photonic properties of bicontinuous cubic microphasesPhysical Review B, 2002
- Metal Oxide Containing Mesoporous Silica with Bicontinuous “Plumber's Nightmare” Morphology from a Block Copolymer-Hybrid MesophaseAngewandte Chemie International Edition in English, 2001
- Core−Shell Double Gyroid Morphologies in ABC Triblock Copolymers with Different Chain TopologiesMacromolecules, 2000
- Direct Measurement of Interfacial Curvature Distributions in a Bicontinuous Block Copolymer MorphologyPhysical Review Letters, 2000
- Cell Crystals: Kelvin's Polyhedra in Block Copolymer MeltsPhysical Review Letters, 1999
- The diagonal bond method: A new lattice polymer model for simulation study of block copolymersThe Journal of Chemical Physics, 1996
- Monte Carlo Simulations of the Phase Behavior of Surfactant SolutionsJournal de Physique II, 1996
- Stabilizing New Morphologies by Blending Homopolymer with Block CopolymerPhysical Review Letters, 1995
- Unusual finite size effects in the Monte Carlo simulation of microphase formation of block copolymer meltsMacromolecular Theory and Simulations, 1995
- The cubic phase region in the system didodecyldimethylammonium bromide-water-styreneLangmuir, 1992