Apparatus for high-pressure studies in chemical kinetics in liquid ammonia from -40 degrees C+150 degrees C (233-423K)
- 1 September 1983
- journal article
- Published by IOP Publishing in Journal of Physics E: Scientific Instruments
- Vol. 16 (9) , 829-831
- https://doi.org/10.1088/0022-3735/16/9/004
Abstract
A high-pressure apparatus (0-700 MPa) is described that allows kinetic measurements (t12/>6 min) on a routine base in liquid ammonia by in situ spectrophotometry. As an illustration preliminary results on the nitrito-nitro linkage isomerisation reaction of the penta-amminecobalt (III) complex are reported. The activation volume for this reaction, at 5 degrees C (278K) is reported.Keywords
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