Synthesis of syn-7-benzyloxy-4-methylbicyclo[2.2.1]hept-5-en-2-one, an intermediate for the synthesis of steroids and tricothecanes; tandem anionic [1,3]–[3,3] sigmatropic rearrangement
- 31 December 1983
- journal article
- Published by Elsevier in Tetrahedron Letters
- Vol. 24 (29) , 2931-2934
- https://doi.org/10.1016/s0040-4039(00)88061-2
Abstract
No abstract availableKeywords
This publication has 12 references indexed in Scilit:
- Preparation and rearrangement of 1,2-dialkenylcyclobutanols. A useful method for synthesis of substituted cyclooctenonesThe Journal of Organic Chemistry, 1982
- Synthesis of a bicyclic precursor to verrucarol: application of a trimethylsilyl-controlled Diels-Alder reaction and Wagner-Meerwein rearrangement sequenceThe Journal of Organic Chemistry, 1981
- Lithiation of cyclopropylcarbinolsJournal of the American Chemical Society, 1979
- Anionic oxy-Cope rearrangements with aromatic substrates in bicyclo[2.2.1]heptene systems. Facile synthesis of cis-hydrindanone derivatives, including steroid analogsJournal of the American Chemical Society, 1978
- Ring expansions of medium-sized ring potassium alkoxides. Unusually fast [1,3]sigmatropic shiftsThe Journal of Organic Chemistry, 1978
- [1,3] Shifts of potassium alkoxides: the bicyclo[3.2.0]heptene–norbornene transformationJournal of the Chemical Society, Chemical Communications, 1978
- Notiz über einen einfachen Weg zum QuadricyclanonEuropean Journal of Organic Chemistry, 1977
- The stereochemistry of sigmatropic rearrangements. Tests of the predictive power of orbital symmetry rulesAccounts of Chemical Research, 1968
- Cyclopentadienone KetalsJournal of the American Chemical Society, 1965
- Copper-Catalyzed Reactions of Benzoyl Peroxide with Norbornadiene Derivatives1,2The Journal of Organic Chemistry, 1964