Oxidative radical addition to alkenes: a convenient route to γδ-unsaturated acids and γ-lactones

Abstract
Diethyl malonate and diethyl alkylmalonates react with olefins and manganese(III) or cobalt(III) acetates in the presence of copper(II) acetate to give diethyl alk-2-enylmalonates which produce upon hydrolysis γδ-unsaturated acids or γ-lactones.

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