Synthesis and characterization of two isomers of decacarbonyl (1,4-dialkyl-1,4-diaza-1,3-butadiene)triosmium: Os3(CO)10(R-DAB). Fluxional behavior of Os3(CO)10(i-Pr-Pr-DAB(4e)) and of the 50e cluster Os3(CO)10(c-Pr-DAB(6e)) containing a 4e donor .rho.,.rho.-N,N' and a 6e donor .rho.-N, .mu.2-N', .eta.2-C:N' bonded R-DAB ligand, respectively.
- 1 October 1988
- journal article
- Published by American Chemical Society (ACS) in Organometallics
- Vol. 7 (10) , 2108-2117
- https://doi.org/10.1021/om00100a005
Abstract
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