Energies Involved in Reorienting Hydration Shells of Ions
- 1 October 1958
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 29 (4) , 851-855
- https://doi.org/10.1063/1.1744600
Abstract
Free energies for reorientation of solvent molecules about ions have been calculated using Marcus' equation for the electrostatic potential and compared with values derived from charge transfer spectra. The low values obtained suggest that electron tunneling between fully hydrated ions is a feasible mechanism contrary to the conclusions of Platzman and Franck.Keywords
This publication has 7 references indexed in Scilit:
- On the Theory of Oxidation-Reduction Reactions Involving Electron Transfer. II. Applications to Data on the Rates of Isotopic Exchange ReactionsThe Journal of Chemical Physics, 1957
- Electrostatic Free Energy and Other Properties of States Having Nonequilibrium Polarization. IThe Journal of Chemical Physics, 1956
- On the Theory of Oxidation-Reduction Reactions Involving Electron Transfer. IThe Journal of Chemical Physics, 1956
- The role of the hydration configuration in electronic processes involving ions in aqueous solutionThe European Physical Journal A, 1954
- The Electron Tunnelling Hypothesis for Electron Ex-change ReactionsThe Journal of Physical Chemistry, 1954
- The Solubility Product of Ferrous Hydroxide and the Ionization of the Aquo-Ferrous IonJournal of the American Chemical Society, 1953
- Photochemical electron transfer with special reference to the formation of hydrogen atoms in aqueous solutionJournal de Chimie Physique et de Physico-Chimie Biologique, 1951