Hydride transfer from cyclohexadienyl anions: the reaction between the hydride Meisenheimer adduct of 2,4-dinitroaniline and 1,3,5-trinitrobenzene
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2
- No. 8,p. 1197-1198
- https://doi.org/10.1039/p29830001197
Abstract
The hydride Meisenheimer adduct of 2,4-dinitroaniline transfers hydride to 1,3,5-trinitrobenzene to form its corresponding hydride Meisenheimer adduct. The reaction is practically irreversible. In dilute solution in dimethyl sulphoxide it exhibits second-order kinetics and the observation of several sharp isosbestic points shows that it occurs without formation of any detectable intermediate species.Keywords
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