Proton hyperfine interactions in the gas-phase E.P.R. spectra of SH (2Π3/2) in two lowest rotational levels
- 1 May 1973
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 25 (5) , 1193-1201
- https://doi.org/10.1080/00268977300101031
Abstract
Gas-phase E.P.R. spectra of the SH radical (2Π3/2) in the J = 5/2 and J = 3/2 rotational levels are described. Analysis of the hyperfine splittings gives the values of axial and non-axial components of the proton hyperfine interaction and the value of the constant d. The frequencies of the two strong lines in the zero-field spectrum are estimated by the use of the observed value of the hyperfine interaction constant d.Keywords
This publication has 19 references indexed in Scilit:
- A measurement of the Λ-doubling transition frequencies for SH in its second rotational levelMolecular Physics, 1972
- Sulfur-33 Hyperfine Interactions in the Gas-Phase Electron Resonance Spectra of Π 2SH and Δ 1SOThe Journal of Chemical Physics, 1971
- Hyperfine interactions in the gas-phase E.P.R. spectra of35ClO (2Π3/2) in theJ= 5/2 andJ= 3/2 levelsMolecular Physics, 1971
- Gas-phase EPR spectra of rotationally excited states of SH and ClO free radicalsJournal of Molecular Spectroscopy, 1970
- Molecular structure of the NS free radical by gas-phase electron paramagnetic resonanceMolecular Physics, 1969
- Radio Spectrum of SHPhysical Review Letters, 1963
- Microwave Zeeman Effect of Free Hydroxyl RadicalsPhysical Review B, 1961
- Microwave Spectra of the Free Radicals OH and ODPhysical Review B, 1955
- Magnetic Hyperfine Structure in Diatomic MoleculesPhysical Review B, 1952
- On-Type Doubling and Electron Spin in the Spectra of Diatomic MoleculesPhysical Review B, 1929