The systematic synthesis of heterobimetallic complexes with only one bridging Ph₂PCH₂PPh₂(dppm) ligand: crystal structures of [(OC)₄Fe(µ-dppm)RhCl(CO)] and [(OC)₃Fe(µ-dppm)(µ-CO)PtBr₂]

1 January 1986

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 1,p. 13-15
https://doi.org/10.1039/c39860000013

Abstract

[(OC)₄Fe(dppm-P)](dppm = Ph₂PCH₂PPh₂) reacts with [RH₂Cl₂(CO)₄] to give [(OC)₄Fe(µ-dppm)RhCl(CO)] with an Fe-Rh bond but no bridging carbonyl group; with [PtBr₂(cyclo-octa-1,5-diene)] the product [(OC)₃Fe(µ-dppm)(µ-CO)PtBr₂] shows some bridging interaction of one of the carbonyl ligands.

Keywords

CRYSTAL STRUCTURE

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The systematic synthesis of heterobimetallic complexes with only one bridging Ph2PCH2PPh2(dppm) ligand: crystal structures of [(OC)4Fe(µ-dppm)RhCl(CO)] and [(OC)3Fe(µ-dppm)(µ-CO)PtBr2]

Abstract

Keywords

The systematic synthesis of heterobimetallic complexes with only one bridging Ph₂PCH₂PPh₂(dppm) ligand: crystal structures of [(OC)₄Fe(µ-dppm)RhCl(CO)] and [(OC)₃Fe(µ-dppm)(µ-CO)PtBr₂]