Palladium Oxidase Catalysis: Selective Oxidation of Organic Chemicals by Direct Dioxygen‐Coupled Turnover
Top Cited Papers
- 22 June 2004
- journal article
- review article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 43 (26) , 3400-3420
- https://doi.org/10.1002/anie.200300630
Abstract
Selective aerobic oxidation of organic molecules is a fundamental and practical challenge in modern chemistry. Effective solutions to this problem must overcome the intrinsic reactivity and selectivity challenges posed by the chemistry of molecular oxygen, and they must find application in diverse classes of oxidation reactions. Palladium oxidase catalysis combines the versatility of Pd(II)-mediated oxidation of organic substrates with dioxygen-coupled oxidation of the reduced palladium catalyst to enable a broad range of selective aerobic oxidation reactions. Recent developments revealed that cocatalysts (e.g. Cu(II), polyoxometalates, and benzoquinone) are not essential for efficient oxidation of Pd(0) by molecular oxygen. Oxidatively stable ligands play an important role in these reactions by minimizing catalyst decomposition, promoting the direct reaction between palladium and dioxygen, modulating organic substrate reactivity and permitting asymmetric catalysis.Keywords
This publication has 285 references indexed in Scilit:
- Synthesis of 1‐(Alkoxycarbonyl)methylene‐1,3‐dihydroisobenzofurans and 4‐(Alkoxycarbonyl)benzo[c]pyrans by Palladium‐Catalysed Oxidative Carbonylation of 2‐Alkynylbenzyl Alcohols, 2‐Alkynylbenzaldehydes and 2‐Alkynylphenyl KetonesEuropean Journal of Organic Chemistry, 2004
- Palladium-Catalyzed Oxidative Kinetic Resolution with Ambient Air as the Stoichiometric Oxidation GasAngewandte Chemie, 2003
- Catalytic Conversions in Water. Part 22: Electronic Effects in the (Diimine)palladium(II)‐Catalysed Aerobic Oxidation of AlcoholsAdvanced Synthesis & Catalysis, 2003
- Catalytic Conversions in Water. Part 21: Mechanistic Investigations on the Palladium-Catalysed Aerobic Oxidation of Alcohols in Water†Advanced Synthesis & Catalysis, 2002
- Kupferproteine: Koordination und Aktivierung von Sauerstoff und seine Reduktion zu WasserAngewandte Chemie, 2001
- Neue Wege zu Wasserstoffperoxid: Alternativen zu etablierten Prozessen?Angewandte Chemie, 1999
- Oxidative coupling of 5-membered heterocycles catalyzed by a Pd(II)-heteropolyacid system in dimethylformamideReaction Kinetics, Mechanisms and Catalysis, 1978
- Oxidative coupling of alkylbenzenes to diaryls catalyzed by the palladium(II)-heteropolyacid systemReaction Kinetics and Catalysis Letters, 1976
- Palladium-catalyzed competitive reaction of aromatic compoundsJournal of Catalysis, 1973
- Isotope effect of aromatic coupling reaction catalyzed by palladium acetateJournal of Catalysis, 1973