Photoinitiated cationic polymerization by triarylselenonium salts
- 1 April 1979
- journal article
- research article
- Published by Wiley in Journal of Polymer Science: Polymer Chemistry Edition
- Vol. 17 (4) , 1047-1057
- https://doi.org/10.1002/pol.1979.170170410
Abstract
Triarylselenonium salts with complex metal halide anions such as BF, AsF, and SbF have been prepared and have been shown to be efficient photoinitiators of cationic polymerization. The photolysis rates of these compounds were studied and their quantum yields of photolysis were reported. Use of specific triarylselenonium salts in the polymerizations of cyclohexene oxide, epichlorohydrin, and 2‐chloroethyl vinyl ether are described.Keywords
This publication has 7 references indexed in Scilit:
- Dye‐sensitized photoinitiated cationic polymerization. The system: Perylene–triarylsulfonium saltsJournal of Polymer Science: Polymer Chemistry Edition, 1979
- A new preparation of triarylsulfonium and -selenonium salts via the copper(II)-catalyzed arylation of sulfides and selenides with diaryliodonium saltsThe Journal of Organic Chemistry, 1978
- Diaryliodonium Salts. A New Class of Photoinitiators for Cationic PolymerizationMacromolecules, 1977
- Photolysis of triarylsulfonium salts in alcoholThe Journal of Organic Chemistry, 1970
- Molecular photochemistry. XXIV. Photocycloaddition of acetone to 1,2-dicyanoethyleneJournal of the American Chemical Society, 1970
- The Photocycloaddition of Acetone to 1-Methoxy-1-butene. A Comparison of Singlet and Triplet Mechanism and Singlet and Triplet Biradical IntermediatesJournal of the American Chemical Society, 1970
- SALTS OF TRIPHENYLSELENONIUM HYDROXIDE1Journal of the American Chemical Society, 1929