NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY: 13 C SPECTRA OF UNSUBSTITUTED INOSITOLS
- 1 July 1969
- journal article
- Published by Proceedings of the National Academy of Sciences in Proceedings of the National Academy of Sciences
- Vol. 63 (3) , 612-614
- https://doi.org/10.1073/pnas.63.3.612
Abstract
The chemical shifts of 13 C in natural abundance have been obtained from nuclear magnetic resonance spectra of scyllo-, myo-, chiro- , and epi -inositols at 15.1 MHz. A set of empirical substitutent parameters were derived and shown to be moderately successful in correlating the 13 C resonance-line positions for these substances. The substituent parameters conform generally to the idea that steric hindrance or porximity effects are of special importance in influencing chemical shifts of carbons in cyclohexane systems.Keywords
This publication has 2 references indexed in Scilit:
- NATURAL-ABUNDANCE C 13 NUCLEAR MAGNETIC RESONANCE SPECTRA OF MEDIUM-MOLECULAR-WEIGHT ORGANIC COMPOUNDSProceedings of the National Academy of Sciences, 1968
- Nuclear magnetic resonance spectroscopy. Benzene-13CJournal of the American Chemical Society, 1967