Dihalogenation of ?-Keto Sulfides. Synthesis of ?-Keto Methyl Esters and ?-Keto S-Phenyl Thioesters

Abstract
α-Keto esters and α-Keto S-Phenyl Thioesters are synthesized from β-keto sulfides by dihalogenation with sulfuryl chloride followed by solvolysis with methanol and acetone/water respectively.

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