An enantiomerically pure α-sulphinyl-N,N-dimethylacetamide: a new, efficient reagent for enantioselective aldol-type condensation
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 1138-1139
- https://doi.org/10.1039/c39830001138
Abstract
Asymmetric synthesis (up to 99%) of β-hydroxy-N,N-dimethylacetamides was achieved starting from aldehydes and an optically active sulphoxide containing synthon, the sense of chiral discrimination depending on the intermediate metal enolate.Keywords
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