The bovine serum albumin–2-phenylpropane-1,2-diolatodioxo-somium(VI) complex as an enantioselective catalyst for cis-hydroxylation of alkenes
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 769-770
- https://doi.org/10.1039/c39830000769
Abstract
The 1:1 complex between an osmate ester and bovine serum albumin was found to be effective as an enantioselective catalyst in the cis-hydroxylation of alkenes, affording diols in up to 68% e.e. and turnover of the catalyst with t-butyl hydroperoxide.Keywords
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