X-ray- and neutron-diffraction measurements on BaMnF4

Abstract
X-ray- and neutron-diffraction measurements on powder and single-crystal samples of BaMnF4 have failed to show any evidence for the distortion with wave vector, in reciprocal-lattice units, q=(0.4,0,0.5) recently reported by Scott, Habbal, and Hidaka. The distorted phase which is observed below 247 K is described by a wave vector q=(ζ,0.5 ,0.5) with ζ incommensurate. There is a small (∼1%) increase in the magnitude of ζ as the temperature is lowered to 100 K, and the detailed temperature dependence of ζ is found to be different on heating and on cooling. The low-temperature distortion is characterized by a single wave vector q=(ζ,0.5,0.5) rather than by a pair of wave vectors (ζ,0.5,0.5) and (ζ,0.5,0.5).