Localized level hopping transport in La(Sr)Cr
- 15 September 1979
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 20 (6) , 2255-2263
- https://doi.org/10.1103/physrevb.20.2255
Abstract
High-temperature measurements have been performed on the electronically conducting oxide system (). The electrical conductivity displayed thermally activated temperature dependence between 300 and 1900 K with activation energies that varied between 0.11 and 0.19 eV. Seebeck coefficients measured over a similar temperature range showed little temperature dependence, an indication that the carrier mobility, rather than the carrier concentration, is thermally activated. The magnetic susceptibility was Curie-Weiss-like between 600 and 1100 K with an effective moment that decreased with an increase in strontium concentration. These results are shown to be consistent with transport by the adiabatic hopping of small polarons.
This publication has 16 references indexed in Scilit:
- Studies of polaron motion: Part II. The “small” polaronPublished by Elsevier ,2004
- Thermoelectric power measurements using analog subtractionReview of Scientific Instruments, 1977
- Structural studies of the (La, Sr) CrO3 systemMaterials Research Bulletin, 1977
- Hopping conductivity in ordered and disordered solids (I)Physica Status Solidi (b), 1976
- Influence of O2 Partial Pressure on Initial Sintering of Alpha Cr2O3Journal of the American Ceramic Society, 1974
- Small-polaron versus band conduction in some transition-metal oxidesAdvances in Physics, 1970
- Seebeck Coefficient of a (ZrO[sub 2])[sub 0.85](CaO)[sub 0.15] Electrolyte ThermocellJournal of the Electrochemical Society, 1968
- Localized versus CollectiveElectrons and Néel Temperatures in Perovskite and Perovskite-Related StructuresPhysical Review B, 1967
- Covalency Criterion for Localized vs Collective Electrons in Oxides with the Perovskite StructureJournal of Applied Physics, 1966
- Absence of Diffusion in Certain Random LatticesPhysical Review B, 1958